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In
1997, the Bluestem Solid Waste Agency decided to examine
the effectiveness of bioreactor technology in cold climates,
such as Iowa's.
By
Curtis L. Hartog, Marten Cieslik, and Timothy J. Hall
A bioreactor
in Iowa will provide valuable study data on the use
of bioreactors in highly variable climates. Iowa, specifically
Cedar Rapids, can experience temperatures higher than
100°F in the summer and as low as -20°F in
the winter.
The Bluestem
Solid Waste Agency, with assistance from the consulting
and engineering firm of Foth & Van Dyke, received
a grant from the Iowa Department of Natural Resources
under the Landfill Alternative Grant Program. The grant
application identified the primary study objectives
as:
- bioreactor
technology as a method of landfill optimization through
reclamation and landfill cell reuse using bioreactors,
- development
of a low-cost composting process suitable for smaller
landfills.
To provide
additional information to evaluate the primary study
objectives, half of the bioreactor includes wastewater
treatment plant sludges to determine if they can enhance
the biological process. At the end of this seven-year
study, the bioreactor will be excavated and waste material
screened to determine levels of decomposition.
The bioreactor
was constructed with a Subtitle D composite liner in
1998. Because of high groundwater levels, the bioreactor
construction required the design and installation of
a groundwater underdrain system to lower natural groundwater
levels to the required 5-ft. separation between groundwater
and compacted clay liner. To determine if wastewater
treatment plant sludges would be beneficial, the bioreactor
was constructed to have two cells, each with its own
leachate collection and recirculation system. When bioreactor
basal liner construction was completed, samples of geotextiles
and geocomposites were placed above the gravel leachate
collection layer to evaluate clogging and survivability
of these materials in bioreactor operations.
Waste placement
in the bioreactor began in December 1998 and was completed
in August 1999. Filling was conducted in a manner typical
for MSW landfills. No preseparation of waste was conducted
except to prohibit construction-and-demolition waste.
Both cells in the bioreactor received approximately
6,000 tons of MSW. Additionally, Cell B received approximately
6,000 gal. of liquid sludges and 70 tons of cake sludges
from the Cedar Rapids Waste Water Treatment Plant. As
they were being filled, a vertical soil berm was constructed
to separate the two cells, two temperature probes were
placed in each cell, and a horizontal landfill gas (LFG)
collection system was installed in each cell and connected
to a common blower.
In September
1999, a 2-ft. soil cap was placed on the bioreactor
to provide both erosion protection and a working surface
for installation of leachate recirculation lines and
removable capsules for evaluation of decomposition through
the process. Leachate recirculation lines and recirculation
pumps were designed to permit targeted recirculation.
Four pumps, which remove liquid from the leachate storage
pond, are each connected to two leachate recirculation
lines that are installed in each cell at a specific
level to target recirculation as needed. Removable capsules
were constructed of plastic netting and filled with
MSW. Each capsule was buried in the waste and will be
excavated throughout the study period. Capsules were
buried in both cells to aid in the evaluation of sludge-addition
effects on bioreactor performance. Final closure of
the bioreactor occurred on November 5, 2000, with the
installation of a tan reinforced polypropylene cap.
The cap will be exposed throughout the study period
so that its survivability through various conditions
can be evaluated. As part of the closure, an operations
plan was developed to aid Bluestem in monitoring bioreactor
parameters.
The operations
plans recommend that the following parameters be monitored
at regular intervals: leachate head on bottom geomembrane,
temperature inside the bioreactor, subsidence, recirculation
pump operation, leachate recirculation line valving,
leachate analytical testing, and LFG parameters.
The operations
plan also details recirculation strategies and winter
operations when recirculation is stopped and the leachate
collection system is closed to prevent freeze damage
and overfill of the leachate storage pond.
During the
first year of full bioreactor operation, the sludge-amended
side of the bioreactor (Cell B) received an additional
72,000 gal. of liquid sludge and 98,000 gal. of water.
The nonsludge side (Cell A) received 86,000 gal. of
water. The total amount of liquids added to the bioreactor
in 2001 was approximately 35,000 ft.3
The addition
of liquids to the bioreactor produced leachate, which
was analyzed weekly for pH, conductivity, and temperature.
During 2001, pH was recorded in the 6.87.0 range
and conductivity stabilized at approximately 12 milliseconds/cm.
Leachate temperature exhibited some variation; high
temperatures around 78°F were recorded in July,
and low temperatures of 62°F were recorded in November.
In 2001, leachate samples were taken in August and October
to monitor specific constituents. Results are provided
in Table 1. Of interest is the reduction of volatile
acids. Increasing volatile acids can affect waste decomposition.
Furthermore, the increase in chemical oxygen demand
(COD) can be attributed to the addition of sludges to
Cell B throughout 2001.
| Table
1. Leachate Analytical Data |
|
Analyte
|
8/9/2001
(mg/l)
|
10/22/2001
(mg/l)
|
|
Acidity
(CaCO3)
|
2,500
|
560
|
|
Alkalinity,
total
|
6,400
|
250
|
|
Chloride,
FIA
|
1,600
|
1,860
|
|
COD,
block digester
|
860
|
2,900
|
|
Ammonia
nitrogen
|
620
|
1.4
|
|
Nitrate
as N
|
43
|
19
|
|
Phosphorous,
total
|
10.4
|
0.97
|
|
Suspended
solids
|
82
|
380
|
|
Total
solids
|
13,000
|
7,000
|
|
Total
volatile solids
|
4,300
|
1,200
|
|
Sulfate
|
100
|
150
|
|
Volatile
acids
|
1,600
|
1,000
|
LFG was also
analyzed in 2001; data on LFG temperature indicate a
steady decline in both cells. This might be a result
of the temperature probe location's being subject ambient
conditions. LFG constitutes were also analyzed in 2001.
Table 2 provides the results from a composite (both
cells) LFG sample. Continued monitoring of LFG constituents
is scheduled through the life of the bioreactor.
| Table
2. Landfill Gas Components |
|
Analyte
|
Value
(ppbv)*
|
|
Methane
|
56
|
|
Carbon
dioxide
|
43
|
|
NMOC
(as hexane)
|
283.33
|
|
Freon
12
|
1,100
|
|
Vinyl
chloride
|
2,700
|
|
Chloroethane
|
500
|
|
Freon
11
|
150
|
|
Freon
113
|
42
|
|
1,1-Dichloroethane
|
79
|
|
cis-1,2-Dichloroethene
|
280
|
|
Benzene
|
230
|
|
Trichloroethane
|
140
|
|
Toluene
|
13,000
|
|
Tetrachloroethene
|
40
|
|
Ethyl
benzene
|
1,200
|
|
m,p-Xylene
|
2,700
|
|
o-Xylene
|
920
|
|
Styrene
|
170
|
|
1,3,5-Trimethylbenzene
|
77
|
|
1,2,4-Trimethylbenzene
|
170
|
|
1,4-Dichlorobenzene
|
68
|
|
Acetone
|
2,100
|
|
2-Propanol
|
210
|
|
Methyl
ethyl ketone
|
5,000
|
|
Hexane
|
1,600
|
|
Tetrahydrofurun
|
2,000
|
|
Cyclohexane
|
870
|
|
4-Methyl-2-pentanune
|
220
|
|
4-Ethyltoluene
|
190
|
|
Heptane
|
1,600
|
|
Hydrogen
sulfide
|
1,700,000
|
| *
All analytes measured in ppbv except methane and
carbon dioxide |
Another critical
reading to evaluate bioreactor performance is waste
temperature. Temperature probes are located at two levels
on each side of the bioreactor. Temperature readings
in 2001 initially were well in the optimum zone for
a bioreactor. By August, temperature readings began
to stabilize throughout the bioreactor to around 80°F
(Figure 1). Further evaluation of temperature data will
determine when the bioreactor is at optimum biodegradation
temperature.
During 2001,
the Bluestem bioreactors performed well. Indicator parameters
confirm that considerable decomposition of waste is
occurring. For 2002, the following goals were established
to further the study of bioreactor technology in the
Midwest:
- Evaluate
alternative temperature sensors to verify existing
sensors are functioning and accurate.
- Add approximately
60,000 gal. of liquid sludge to Cell B and 50,000
gal. of water to Cell A.
- Install
flow meters on recirculation lines to better quantify
recirculation.
- Continue
to conduct analytical testing on leachate and LFG.
- Exhume
one capsule from Cell A to determine decomposition
rate.
With additional
data from 2002, bioreactor performance can be optimized,
speeding decomposition and furthering the study objectives.
Curtis
L. Hartog, P.E., is head environmental engineer and
Marten Cieslik, P.E., is senior project manager with
Foth & Van Dyke, headquartered in Green Bay, WI.
Timothy J. Hall, P.E., is with the Iowa Department of
Natural Resources.
MSW
- November/December 2002
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