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By Gary R. Minton

Part
I: Basins
Part
2: Fine-Media Filters
Part
3: Grass-covered, flow-through treatment swales and strips
It has been 25 years
since the first community in the United States established the requirement
for the postdevelopment treatment of stormwater from new developments.
Since then, many manuals and handbooks have been published by local,
regional, and state governments identifying acceptable treatment
systems and design criteria. Initially, few of these design criteria
were supported by laboratory or field research. With numerous studies
completed over the past two decades, it is timely to reexamine some
of these criteria.
The first three articles
in this series focused on the removal of settleable sediment with
attached pollutants by three systems: basins, fine-media filters,
and flow-through swales. The final two articles consider how design
criteria should differ when the removal of dissolved pollutants
is also an objective. This article considers wet basins, and the
final article considers fine-media filters and flow-through swales.
Background
Pollutants with commonly 50% or more as dissolved include zinc,
copper, cadmium, and nitrogen (Minton 2002, Pitt et al. 2004). Phosphorus
is generally less, 25% to 50%. While most pesticides and hydrocarbons
are substantially attached to settleable solids (sediment), the
dissolved concentrations may still be toxic. Some pesticides and
herbicides such as atrazine are very soluble. Table 1 presents median
values for national data (Pitt et al. 2004). The ranges reflect
differences between land uses. Generally, zinc represents 75% of
the metals.
| Table
1. Dissolved Concentrations of Pollutants |
|
Pollutant
|
Median, µg/L
|
|
Metals
|
45-130
|
|
Phosphorus
|
110-170
|
|
Nitrogen
|
90-140
|
Separation into dissolved
and particulate fractions is a physical, not a chemical, definition.
Dissolved fractions are the constituents that pass through the laboratory
filter, typically 0.45 microns. Small particles, or colloids, pass
through the filter with pollutants attached. In wet basins, soluble
pollutants are removed by sorption/precipitation in the soil and
by plant uptake. Colloids do not settle well, if at all, and are
essentially unfilterable. However, they attach to plant surfaces
and may coagulate and settle naturally given time. For this article
we make this distinction between dissolved and soluble constituents:
The former pass through a laboratory filter, and the latter are
the free ions or ionic complexes of the pollutant.
The many forms of each
pollutant complicate their removal. Dissolved nitrogen is present
as nitrate, ammonia, and organic-bound ammonia, but primarily the
last two. Dissolved phosphorus is present as orthophosphate, free
or bound in organic matter. Metals are present in ionic complexes
and sorbed to soluble humic organics.
Our focus is how design
criteria differ for surface wet basins: ponds and constructed wetlands.
Minimal removal of dissolved pollutants is expected in extended
detention basins and wet vaults, the former because the stormwater
leaves the facility too quickly, the latter because of the lack
of soils and biota. The presumed benefit of wetponds and constructed
wetlands is the removal of dissolved pollutants. There are potentially
adverse effects of wet basins: greater space, mosquitoes, thermal
enrichment, and invasive species. This suggests that wet basins
be selected and sized with caution and that design criteria recognize
potential adverse impacts.
Configurations
Manuals contain many configurations, divided into wetponds
and wetlands. In general, the surface area of a wetpond is 75% or
more deep open water. A wetland is the reverse with 15% to 25% deep
open water. There are three general schemes of plant coverage: along
the lateral edges (fringe) with open water between inlet and outlet
(a pond); complete coverage (a shallow wetland), perhaps with open
water forebays and afterbays; and alternating transverse bands of
deep open water and shallow vegetated benches (pond/wetland). There
are also treatment train concepts such as a wetpond
followed by a shallow wetland.
Shallow wet basins placed
on soil are surface flow wetlands; the stormwater passes through
the facility above the soil. Diffusion of the pollutants within
saturated soil is very slow. To enhance the waters contact
with plant roots, gravel is used in lieu of soil. At the facility
inlet, the stormwater is directed downward and through the gravel
bed. The configuration is called subsurface flow (SSF). This system
has additional advantages. The invert is placed a few inches below
the top of the gravel to remove mosquito habitat. SSF wetlands may
be attractive in regions with cold winters, avoiding the effects
of freezing, and in semi-arid areas, reducing evaporation. Gravel
provides a firm work area to harvest foliage. The bed is shallow,
2 to 3 feet (0.6 to 1 meter). Improving the waters direct
contact with the roots and gravel might reduce the residence time,
and therefore basin volume may be less. However, the media offsets
the reduction in liquid volume. An additional concern is clogging
of the media over time by incoming sediment.
Each of the configurations
described above may have either a free-flowing or a restricted outlet
to create an extended detention (ED) layer above the permanent pool.
Whether dividing the treatment volume into a wet pool and an ED
layer benefits performance has not been definitively established.
The ED layer is of value in configurations with fringe vegetation,
given its adverse effect on hydraulic efficiency (Wong et al. 1999).
The ED layer may improve hydraulic efficiency by forcing stormwater
into thickly vegetated areas and into the corners of the basin.
The hydraulic benefit may be most relevant in climatic regions with
high-intensity rainfall.
Conversely, the disadvantage
of the ED layer is that much less stormwater is retained between
storms. Given the slowest of the processes of dissolved pollutant
removal, retaining stormwater between storms is important. The more
stormwater retained between storms, the greater the load reduction
of dissolved pollutants. Some recommend the basin volume be primarily
extended detention with less than 20% as wet pool (Wong et al. 1999).
The objective is periodic drying with enhanced aerobic degradation
of organic matter, believed necessary for long-term performance,
particularly for phosphorus. However, this necessitates a substantial
drawdown time of about 200 hours (Wong et al. 1999), presumably
to give a residence time similar to wet basins.
| Figure
1. Unit Processes in Wet Basins |
|
Water
|
Aerobic
|
Dissolved
oxygen (DO) >3 mg/L
|
Eh
> 300 mv
|
- Diurnal
pH: CaCO3/PO4 precipitation
- Bacteria
nitrification - organic N to NH3, NH3 to
NO3
- Aerobic
reduction of organics
- Free
floating plant/algae uptake
- Algae/bacteria
biofilm uptake of N,P, metals
-
Sorption of colloids to plants/biofilm
|
|
Soil
|
Aerobic
|
DO
1 to 3 mg/L
|
Eh
> 300 mv
|
- Bacteria
nitrification - organic N to NH3, NH3to
NO3
-
Metals sorb to organics in soils
-
Precipitation PO4 with Al, Fe+3, Ca
in soil
- Sorption
of toxic organics to humic organics
- Aerobic
reduction of organics
- Rooted
plant uptake
-
Metals sorb to Fe-Al Oxide complexes
|
|
|
Facultative
|
DO<1
mg/L
|
Eh
= 100 to 300
mv
|
- Bacteria
denitrification - NO3 to N2
- Reduction
of Fe+3 to Fe+2 with loss of PO4
-
Precipitation PO4 with Al, Ca in soil
- Rooted
plant uptake
|
|
|
Facultative
|
DO<1
mg/L
|
Eh
= -100 to -100
mv
|
- Reduction
of Fe+3 to Fe+2 with loss of PO4
|
|
|
Anaerobic
|
DO
0 mg/L
|
Eh
= -200 to -100
mv
|
- Reduction
of SO4 to S-
- S-
complex with metals
- Anaerobic
reduction of organics
- Rooted
plant uptake
|
Whether a particular
configuration has a clear advantage is unknown. A constructed wetland
is perceived to be better than a wetpond because of the greater
vegetation coverage, but the validity of this perception has not
been definitively established. Wetlandsfully vegetated or
with alternating deep/shallow transverse bandsare likely more
effective than ponds at removing suspended solids during storms
and colloidal material between storms (Wong et al. 1999, Breen and
Wong 2000). This may be the most appropriate configuration if removing
dissolved nitrogen is the objective (Stearman et al. 2003). In contrast,
a fully vegetated system may be necessary for maximum phosphorus
removal. However, whether wetlands are more effective than wetponds
at removing dissolved pollutants has not been established. The marginal
benefit, if it exists, may not be justified, particularly considering
the potentially greater adverse effects previously listed.
Removal Processes
It is commonly believed that plant growth is the primary removal
process. This may be true initially when plant infilling occurs.
However, research with stormwater and wastewater wet basins shows
that most of the pollutants accumulate in the soil or are transformed
and removed by bacterial processes. What plants remove is located
primarily in their roots. Plants provide indirect benefits as described
below.
The biological and chemical
processes of a wet basin are illustrated in Figure 1 (Minton 2002),
which indicates there are many processes other than uptake by plants
that may be important removers of pollutants. Note in Figure 1 the
thin surface layer of aerobic soil. In natural wetlands the thickness
may be as much as an inch (25 millimeters), though its thickness
in stormwater basins is unknown. It may decrease as the facility
matures with the accumulation of organic matter. The thin aerobic
layer is very important to the removal of soluble phosphorus and
the transformation of organic nitrogen and ammonia to nitrate. Beneath
this layer the soil is anaerobic because the consumption of dissolved
oxygen by bacteria is more rapid than diffusion from above.
Metals sorb to humic
organics and aluminum/ferric iron/manganese oxides in the upper
aerobic layer. Metals also diffuse lower into the soil where they
complex with sulfide produced by sulfate reducing bacteria. Pesticides
sorb to clays and humic organics. Bacteria in the soil are likely
dominant removers of nitrogen. Bacteria change organic nitrogen
to ammonia (ammonification) and ammonia to nitrate (nitrification)
under aerobic conditions. Some ammonia is lost directly to the atmosphere
by volatilization, but this is significant only if the pH is high,
which can occur during summer afternoons with algal activity. Other
bacteria change the nitrate to nitrogen gas (denitrification) but
only in the presence of low dissolved oxygen. Anaerobic conditions
enhance the removal of some pesticides and toxic organics (Kao,
Wang, and Wu 2001; Stearman et al. 2003).
In treatment wetlands,
the thin aerobic surface layer may be more dynamic than in natural
wetlands, frequently becoming anaerobic. During the summer high
water temperatures increase the rate of degradation of organic matter
by bacteria. The water becomes anaerobic (Huneycutt 2002) particularly
in deeper wetponds with thermal stratification. Soluble phosphorus
and metals previously removed are released to the overlying water
through the dissolution of ferric iron phosphate (McKee and McKevlin
1993) and ferric-manganese-metal complexes (Reddy and Patrick 1983),
respectively. Contributing to this dynamic is algal growth stimulated
by nitrogen and phosphorus from the stormwater. During the day algal
growth produces dissolved oxygen. The pH is driven upwards from
the consumption of carbon dioxide, beneficial to calcium phosphate
precipitation, and ammonia volatilization. However, at night the
algae respire, consuming the dissolved oxygen. The result is diurnal
swing at the soil surface: aerobic-anaerobic-aerobic. As a consequence,
the performance of stormwater basins may not be maximized (Diab,
Kochba, and Avnimelech 1993; Herskowitz, Black, and Lewandowsk 1987).
Plants use what we consider
to be pollutants as nutrients for growth. Their concentration in
plant biomass responds directly to the concentration in the water:
The higher the concentration of the nutrient in the water, the greater
the concentration in the biomass, to a point that is likely above
the concentrations of nutrients observed in stormwater (Reddy and
DeBusk 1987). The relationship varies significantly depending on
plant species, plant health, and the season. Regardless, research
consistently shows that the bulk of removed metals are found in
the soil and that most nitrogen removal is by bacteria (Kadlec and
Knight 1996, Minton 2002). However, the proportion removed by direct
plant uptake and soil processes depends on the chemistry of the
soil and the maturity of the basin.
The primary benefit of
rooted plants is indirect. When they die, plants provide organic
matter to which pollutantsin particular metals, pesticides,
and hydrocarbonssorb. Bacteria that nitrify and denitrify
require carbon from decaying organic matter for growth. Plants pump
dissolved oxygen from their foliage downward to create an aerobic
zone around their roots, increasing the volume of aerobic soil.
The effect varies with the species, plant health, and season (Urbanc-Bercic
and Gaberscik 1999). This process benefits the formation of nitrate,
the sorption/precipitation of phosphorus, and the sorption of metals
to aluminum/ferric iron/manganese oxide complexes. Plants increase
the removal of pesticides by supporting increased densities of bacteria
(Thullen, Sartoris, and Walton 2002).
Dissolved pollutant removal
occurs in the overlying water. Free-floating algae consume pollutants
as nutrients, die, and sink to the bottom. However, their role may
be counterproductive, because the bulk of the algae may exit the
basin during storms, taking pollutants that would otherwise have
diffused into the soil, the preferable route. Algaes most
important role may be at the surface of plant foliage. A biofilm
of bacteria and algae grows on the plant foliage, consuming nutrients;
sub-micron colloids attach to this film (Lawrence and Breen 1998).
Plant surfaces have a much higher density of nitrifying bacteria
than the water. This may be particularly important if the diurnal
swing of the thin aerobic soil layer previously described occurs
(Davido and Conway 1989).
It is commonly stated
that the wet pool must not be allowed to disappear between storms
through infiltration and/or evaporation. Loss is prevented with
a liner and a drainage area of sufficient size to provide base flow.
As a consequence, wet basins are discouraged for small drainage
areas and in semi-arid climates. Temporary exposure of the normally
anaerobic soil to dissolved oxygen significantly increases the degradation
of accumulated organic matter, releasing pollutants. A portion of
the sorbed metals and phosphorus may be transformed to forms more
susceptible to desorption (Olila, Reddy, and Stites 1997; Saeki,
Okazaki, and Matsumoto 1993). It is perhaps feared that the released
pollutants are lost in subsequent storms. However, they likely migrate
deeper in the soil where permanent sequestering occurs (Urbanc-Bercic
and Gaberscik 2001). Regardless, it has not been established that
periodic drying reduces performance. The volume of a wet basin is
substantially greater than the volume of most storms. The first
storm following a dry period partially fills the basin, providing
time for released pollutants to be re-sequestered. As noted previously,
some recommend that the basin be designed to dry frequently. A constant
base flow can be detrimental. What is removed during storms may
be lost in the base flow from desorption and/or plant litter (Oberts
1997). There is no evidence to suggest that wet basins should be
discouraged for small drainage areas and in semi-arid areas.
A wetland/wetpond system
is complex. Only a small portion of the pollutants in the effluent
of the system during each storm is from the influent of that storm.
Most has moved through the soil and plants in a continual process
of uptake and release, escaping the facility with each storm and
in the base flow if present. The dynamic turnover also suggests
that plants establish background concentrations below which further
reduction cannot be achieved. Experience from wastewater treatment
suggests 1 to 2 mg/L for nitrogen (Kadlec and Knight 1996). Total
phosphorus (TP) background may be 0.010 to 0.050 mg/L (Richardson
and Qian 1999). A survey of 13 wet basins found a mean concentration
of TP of 0.080 mg/L (Carr and Kehoe 1997). The background concentrations
are a reflection of plant activity and the resistance of the dissolved
organically bound pollutants to degradation (Newman and Lynch 2001).
Alternative Design
Criteria
Stormwater manuals do not distinguish the removal of total
suspended solids (TSS) from the removal of dissolved pollutants.
Furthermore, manuals specify the volume of wetponds and wetlands
the same as the volume for extended detention basins. In the
first article of this series it was established that a wet basin
can be considerably smaller yet meet the typical TSS performance
goal of 80%.
As the bulk of the sediment
is removed during each storm, performance is best related to the
ratio of the volume of the basin to the runoff volume of the mean
storm (Vb/Vr) (USEPA 1986). This approach is appropriate for wet
basins where the sole objective is the removal of TSS and attached
pollutants. In contrast, it is likely the removal of dissolved pollutants
occurs primarily between storms. Therefore, the volume of the basin
is best related to the annual runoff depth. Sizing will likely differ
for each pollutant type: phosphorus, nitrogen, and metals. If the
management goal is the general removal of dissolved pollutants,
the sizing criterion that gives the largest basin takes precedence.
Several alternatives
for a basic sizing criterion are discussed below: storm runoff depth,
hydraulic residence time, hydraulic loading rate, pollutant loading
rate, kinetic removal rate, and process model.
Storm Runoff Depth:
This design criterion is currently specified in most manuals to
size both extended detention basins and wet basins. A common design
depth is 1 inch to treat 90% of stormwater generated over time.
The volume, V, is determined by V = RaRcA
where Ra is the runoff design depth, Rc
a runoff coefficient to account for pervious surfaces, and A
the drainage area. Different depths can be specified for different
objectives: TSS or dissolved. However, as noted in the first article,
the concept is not relevant to wet basins. A design criterion that
more explicitly relates basin size to dissolved pollutant removal
is perhaps more appropriate.
Hydraulic Residence
Time (HRT): Soil and plant processes are slow, as is diffusion
in saturated soils, suggesting the importance of time. Larger basins
with an HRT of 14 days have been recommended for improved phosphorus
removal (Hartigan 1988). The
volume of the basin is determined by V = RaRcAHRT/365
where Ra is the annual runoff depth, Rc
the runoff coefficient, A the drainage area, and HRT
the hydraulic residence time in days. HRT is not the residence time
during each storm . It represents the average time the water
resides in the basin, including the time between storms. HRT has
been referred to as the average annual residence time.
Annual rainfall runoff
in areas of interest ranges from 10 to 60 inches (25 to 150 centimeters)
(USEPA 1989). With an HRT of 14 days, the unit volume (V/A) ranges
from 0.4 to 2.4 inches (1 to 6 centimeters). This provides volume
ratios (Vb/Vr) of about 0.7 to 3. In the first article, a Vb/Vr
of 1 was suggested as adequate for the removal of TSS. In semi-arid
areas with low annual rainfall, like the Southwest and the Rocky
Mountain states, the HRT for a Vb/Vr of 1 is about equal to or substantially
greater than 14 days. In contrast, the HRT is less than seven days
in wetter regions. In wetter regions the basin must be larger, by
a factor of two or three, for an HRT of 14 days. The HRT as represented
here is the nominal HRTthat is, the basin volume divided by
the average inflow rate. The actual HRT is less, reflecting hydraulic
inefficiency. How much less depends on the configuration.
Hydraulic Loading
Rate (HLR): If soil and rooted plants are central to pollutant
removal, the surface area of the basin should be explicitly recognized.
This is accomplished by considering the areal loading rate. There
are two options: HLR and pollutant loading rate (PLR). The first
is discussed here. The
facility surface area, Af, is determined by Af
= RaRcA / 365HLR where Rais
the annual runoff depth, Rcthe runoff coefficient,
Athe drainage area, and HLRthe hydraulic
loading rate in centimeters per day. HLR does not refer
to the loading rate during a storm but rather the average rate over
a year, or the average annual hydraulic loading rate. The numerator
represents the total annual volume of stormwater entering the facility.
The design method implies the selection of a depth that gives a
residence time, HRT, for satisfactory performance.
Limited studies (Abtew
et al. 2004, Bulc and Slak 2003, Newman and Lynch 2001) of stormwater
wetlands suggest satisfactory nutrient removal at HLR values of
1 to 10 cm/day, which is similar to the more substantial experience
with wastewater treatment (Kadlec and Knight 1996). A wetland with
an HLR of 2 cm/day with an average depth of 1 foot (0.3 meters)
has an HRT of about 14 days. At these design values, the surface
area of the wet basin varies widely across the United States, from
about 100 to 800 square feet per impervious acre (approximately
22 to 175 m2/ha), the surface area increasing with annual rainfall.
For a wetpond with an average depth of 5 feet (1.5 meters), the
HLR is 11 cm/day for an HRT of about 14 days. The surface area is
proportionally less.
Pollutant Loading
Rate: Using the same value for any of the design criteria introduced
previously implies a constant median pollutant concentration. However,
the concentration differs between climatic regions and between land
uses within each region (Pitt et al. 2004). The alternative design
criteria introduced to this point obscures what is perhaps the more
relevant consideration, the pollutant loading per unit surface area
or PLR. The facility surface
area, Af , is determined by Af = RaRcAPm/PLR
where Ra is the annual runoff depth, Rc
the runoff coefficient, A the drainage area, Pm
the median influent pollutant concentration, and PLR
. The numerator represents the total annual pollutant load
to the facility. The design criterion implies the selection of a
depth that gives a residence time, or HRT, for satisfactory performance.
Like HRT, the PLR and HLR presented here are nominal criteria. The
actual values differ from the nominal to the extent of hydraulic
inefficiency.
The PLR differs with
the pollutant: nitrogen, phosphorus, and metals (in the aggregate)
given their different median concentrations. Performance studies
will likely show the unit area needed for each of the pollutants
is the same. Not clear at this point is whether the PLR should be
based on the total or the dissolved concentration. A portion of
the particulate form solubilizes after entering the basin. Little
is known about the potential for solubilization, but there are methods
available for analysis (Minton 2002).
PLR allows consideration
of a question not yet discussed: short- versus long-term performance.
It is likely that wet basins remove nitrogen and metals over the
long term, improving as the facility matures. This does not appear
to be true for phosphorus. The chemical sorption capacity is reached;
how soon depends on the soil chemistry. There is no evidence that
as iron and aluminum in the influent accumulate in the basin they
factor in phosphorus removal. Absent harvesting of vegetation, the
facility must be sized based on the production of plant debris resistant
to long-term degradation. Extensive experience (Richardson and Qian
1999) with wastewater wetlands suggests a sequestering rate of 0.25
to 1 g/m2/yr, with a frequently suggested value of 0.5.
Limited studies of stormwater
wetlands seem consistent with wastewater experience (Abtew et al.
2004, Moustafa et al. 1996). One study found 90% removal at a PLR
of about 0.50 g/m2/yr, decreasing to 63% removal at about
4.2 (Abtew et al. 2004). Mean annual outflow concentrations ranged
from 25 to 53 _g/L (micrograms per liter). The system continued
to remove phosphorus after eight years. In contrast, another pond-wetland
facility experienced loadings of about 5 g/m2/yr. It
removed 85% of the TP during its first year but none when tested
10 years later (Oberts 1997). While removal during storms continued,
phosphorus was lost in the base flow.
Consider these assumptions:
PLR of 0.5 g/m2/yr; medium concentrations of TP by climatic
region (Pitt et al. 2004); and 50% of TP bioavailable (dissolved
plus desorption). The
surface area of a wet basin ranges from about 500 to 3,000 square
feet per impervious acre (about 110 to 650 m2/ha), about
1% to 6% of the drainage area depending on the climatic region.
The HRT for an average basin depth of 2 feet (0.6 meters) is about
four to 16 days. Perhaps sorptive media can be added to soil or
gravel to allow reduction in surface area.
It may be feasible to
decrease the surface area if harvesting occurs regularly. But this
decreases the HRT if depth is held constant. Perhaps the HRT can
be less than 14 days. It may be that the greater the surface area
in proportion to the volume, the lower the HRT needed to achieve
the desired performance. Phosphorus in foliage is 0.1 to 0.4 g/m2
in natural wetlands (Kadlec and Knight 1996) but likely higher in
stormwater wetlands (Reddy and DeBusk 1987). The effectiveness and
appropriate harvest methods require further study as to their effect
on short-term performance (Gu et al. 2001, Urbanc-Bercic and Gaberscik
1999).
Loss of long-term performance
is not likely with nitrogen and metals. For these pollutants, a
wetpond with transverse shallow vegetated benches may perform as
well, requiring less space than a shallow wetland at the same HRT.
It is possible that a wet basin sized for TSS removal need not be
larger to obtain the maximum practical removal of nitrogen or metals,
depending on the climatic region. With a lower limit of 1 to 2 mg/L,
modest removal for nitrogen is expected (England 2001). Consequently,
a shallow marsh wetland (low PLR) may gain little and may decrease
performance. Based on the experience of wastewater wetlands (Kadlec
and Knight 1996) and recognizing the lower concentrations in stormwater,
PLR values for nitrogen of 3 to 4 g/m2/yr may be appropriate. However,
because of the effect of plants on the background concentration,
higher loadings are likely possible without degradation of effluent
quality.
Kinetic Removal Rate:
Pollutants are removed at a kinetic removal, or reaction, rate in
a wet basin. The concentration decreases exponentially as the water
passes through the basin. Reduction is greatest in the entry area
of the basin, gradually decreasing toward the outlet. Kinetic equations
are commonly used in the sizing of wastewater wetlands. The simplest
form of a kinetic equation is Ce = Cie-kHRT
where Ceis the effluent concentration, Cithe
influent concentration, k
the kinetic removal rate coefficient, and HRTthe
hydraulic residence time. The equation assumes a first-order reaction
rate; that is, for the same value of kHRT, the
removal efficiency is the same irrespective of the influent concentration.
Research suggests that kis dependent on influent concentration
(Kadlec 2000). Therefore, values from wastewater treatment are not
applicable. A study of experimental stormwater wetlands found kfor
phosphorus to vary by a factor of six (Bays et al. 2001). The factors
affecting the value included presence/absence of vegetation, water
depth, type of soil, HLR, and PLR. No relationships between the
factors were developed.
More complex equations
than the one above include influent concentration, HRT, background
concentration, HLR, and/or kinetic rates other than first order.
The approach is complicated further by the multiple forms of nitrogen
and phosphorus that have different kinetic removal rates. The concept
may not be useful for either nitrogen or metals. As noted previously,
influent and background concentrations are similar. The limitation
with metals is their low influent concentrations, except for zinc.
Process Model: All previous
design criteria are empirical black box constructs within
which the multiple processes occur. These can be called implicit
models. Alternatively, the major processes are explicitly described
mathematically (Fletcher 2004; Lawrence and Breen 1998; Thullen,
Sartoris, and Walton 2002). Using appropriate input coefficients
for each process, the system is sized as a function of desired performance.
One model includes the
removal of all pollutant forms: particulate, colloidal, and soluble,
by sedimentation, attachment, sorption/precipitation, and plant
and biofilm uptake (Lawrence and Breen 1998). Presented in Figures
2 and 3 are example outputs for settleable solids and TP, respectively.
Three sizes of sediments are shown: Fine represents the colloidal.
While TP is shown, removal of soluble and colloidal fractions is
simulated explicitly. The figures indicate an HRT less than 15 days
may be sufficient. The process model has the advantage of showing
key relationships explicitly, important to understanding the effect
of size on performance.
| Figure 2. Simulation of the Removal of Settleable Solids (Lawrence and Breen 1998) |
 |
| Figure 3. Simulation of the Removal of the Total Phosphorus (Lawrence and Breen 1998) |
 |
A concern with process
models is the many decisions to be made on input coefficients for
the particular climatic region. Studies by region are sparse or
nonexistent. Studies to date of both stormwater and wastewater suggest
substantial variation in the coefficients, reflective of a complex
chemical-biological ecosystem. But this observation is valid for
all alternative design criteria introduced.
Final Observations
Regardless of the design criterion selected, arriving at the
appropriate design value is a daunting task. The processes of wet
basins are complex, particularly those of wetlands. Drawing general
conclusions from specific studies is fraught with uncertainty. Studies
must be comprehensive, structured to consider all processes and
the condition of the soil before saturation. Evaluations must occur
over an extended period of time as the test facility matures. The
ability to draw firm conclusions from field or laboratory studies
is complicated by the differing forms of the pollutants of interest
and the low influent concentrations near the detection limit. Few
existing published studies provide the necessary information to
calculate values for the alternative design criteria discussed in
this article. It is hoped this discussion will spur researches to
include the necessary information in their reports.
Bigger is not necessarily
better. As suggested by Figures 2 and 3, a point of diminishing
returns exists at which the incremental increase in the size of
a basin does not provide a demonstrable increase in performance.
The gradual slopes in Figures 2 and 3 indicate that the point is
not obvious. Regardless, the design coefficients should be based
on incremental cost versus incremental performance, not incremental
size.
Bigger can be worse.
A basin surface area in excess of what is needed for effective removal
of dissolved pollutants might result in the increase of relevant
pollutants in the effluent. There is the possibility of too great
a mass of emergent plants with loss of the pollutant bound to soluble
and particulate organic matter emanating from the plants. Annual
cleaning of the forebay may be appropriate to decrease solubilization
of pollutants from imported organic matter, thereby reducing loading
on the wet basin.
Given the importance
of the soil and the effect of its variation in chemistry on performance
(Hsieh and Coultas 1989, Newman and Pietro 2001), soils should be
tested prior to flooding. Agricultural lands heavily fertilized
may be saturated with phosphorus or nitrogen (Pant et al. 2002).
Phosphorus and metals original to the soil may be lost as previously
described upon basin filling. As a consequence, the wet basin may
be a net source rather than a sink. Laboratory methods exist that
define susceptibility to release (Minton 2002). Testing may indicate
corrective actions to be taken in the design.
Summary
When considering setting goals for the removal of phosphorus,
nitrogen, or metals, the importance of the dissolved fraction should
be recognized. The sizing criterion should be distinct from that
used to size wet basins for the removal of TSS with associated particulate
pollutants.
A shallow marsh wetland
is likely the most appropriate wet basin configuration for dissolved
phosphorus. Whether this configuration is appropriate for dissolved
nitrogen and metals has not been demonstrated; a wetpond primarily
of deep water with alternating transverse bands of shallow vegetated
benches might be more appropriate. It requires less space, and a
lower HRT than for phosphorus may be feasible.
It is has not been definitively
demonstrated that splitting the basin volume into permanent wet
pool with extended detention is appropriate. To improve hydraulic
efficiency, it is likely appropriate for a shallow marsh but not
for the suggested wetpond configuration.
The relative sizes of
the three basin typesextended detention, wetpond, and wetlandwill
differ with the selected design criteria and climate. Enhanced treatment
wet basins as proposed here may be similar in volume to extended
detention basins as currently sized but likely with larger surface
areas. Except in semi-arid regions, wet basins for the removal of
dissolved pollutants will require larger volumes, larger surface
areas, or both than if the sole focus is 80% removal of TSS.
Process models should
be used to structure pilot and full-scale field studies. With criteria
specific to different climatic regions, regulators can use process
models to conduct rational cost-benefit analyses. Ideally, the understanding
of such models as well as the alternative design criteria discussed
in this article will result in the inclusion of all necessary information
in performance studies. This is essential if we are to understand
the relationship between each alternative criterion and performance.
It is proposed that pollutant
loading rate combined with an appropriate minimum hydraulic residence
time be used as the basis for sizing wet basins. The other design
criteria may do as well, but the suggested combination provides
a more explicit view of the key processes except for a process model.
With time, laboratory and field studies will provide definitive
design values for each pollutant type, although the value of 0.5
g/m2/yr is likely appropriate for phosphorus. We will also likely
find that the cost-effective unit volume and unit area requirements
differ with each pollutant. Given the complexity of the processes
in wet basins, particularly wetlands, professional judgment will
always be central to the selection of design values.
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SW
May/June 2005
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